Kitty Oppenheimer: Can you explain quantum mechanics to me?
J. Robert Oppenheimer: Well, this glass, this drink, this counter top, uhh.. our bodies, all of it. It’s mostly empty space. Groupings of tiny energy waves bound together.
Kitty Oppenheimer: By what?
J. Robert Oppenheimer: Forces of attraction strong enough to convince us [that] matter is solid, to stop my body passing through yours.
— IMDB quote from Oppenheimer
Flash forward to 2023, where Mario Barbatti is a theoretical chemist and physicist researching light and molecule interactions. He’s also a professor of chemistry at Aix Marseille University in France. Writing this week for Aeon, Barbatti argues that “there are no empty spaces within the atom.
“The empty atom picture is likely the most repeated mistake in popular science.”
It is unclear who created this myth, but it is sure that Carl Sagan, in his classic TV series Cosmos (1980), was crucial in popularising it. After wondering how small the nuclei are compared with the atom, Sagan concluded that “[M]ost of the mass of an atom is in its nucleus; the electrons are by comparison just clouds of moving fluff. Atoms are mainly empty space. Matter is composed chiefly of nothing.” I still remember how deeply these words spoke to me when I heard them as a kid in the early 1980s. Today, as a professional theoretical chemist, I know that Sagan’s statements failed to recognise some fundamental features of atoms and molecules…
Misconceptions feeding the idea of the empty atom can be dismantled by carefully interpreting quantum theory, which describes the physics of molecules, atoms and subatomic particles. According to quantum theory, the building blocks of matter — like electrons, nuclei and the molecules they form — can be portrayed either as waves or particles. Leave them to evolve by themselves without human interference, and they act like delocalised waves in the shape of continuous clouds. On the other hand, when we attempt to observe these systems, they appear to be localised particles, something like bullets in the classical realm. But accepting the quantum predictions that nuclei and electrons fill space as continuous clouds has a daring conceptual price: it implies that these particles do not vibrate, spin or orbit. They inhabit a motionless microcosmos where time only occasionally plays a role…
A molecule is a static object without any internal motion. The quantum clouds of all nuclei and electrons remain absolutely still for a molecule with a well-defined energy. Time is irrelevant… Time, however, comes into play when a molecule collides with another one, triggering a chemical reaction. Then, a storm strikes. The quantum steadiness bursts when the sections of the electronic cloud pour from one molecule upon another. The clouds mix, reshape, merge, and split. The nuclear clouds rearrange to accommodate themselves within the new electronic configuration, sometimes even migrating between molecules. For a fraction of a picosecond (10-12 seconds or a billionth of a millisecond), the tempest rages and reshapes the molecular landscape until stillness is restored in the newly formed compounds.